Why is the mailer asking you why you're unsubscribing a punishable offense? Mailchimp does this by default on any of their unsubscribe pages (which come after you've been unsubscribed).
If a service puts me on a subscription list without asking me, and then at the unsubscription page throws a questionnaire at me as to why I am unsubscribing, I take that as dishonest behavior.
Obviously I am unsubscribing because I never subscribed in the first place!
Depending on how completely unrelated the subscription is to whatever I signed up for (say I signed up for online image hosting, and they start sending me emails about their fantastic paid backup service) then I mark it as spam even if the unsubscribe button is easy and single-click.
And for companies like MailChimp, it's a way to identify customers who are spamming people, and (hopefully) closing their accounts. If a high percentage of users are responding to the feedback form with "I never subscribed" then it's worthy of investigation.